The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.8b10069. Instructions for using Copyright Clearance Center page for details. Dehydrogenation- It means removal of hydrogen from the saturated hydrocarbon to make it unsaturated.
Guofu Zhang, Yiyong Zhao, Lidi Xuan, Chengrong Ding. Both dehydration and dehydrogenation rates are enhanced in proportion to the vanadia loadings up to about 2 wt %.
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Yogesh Thopate, Richa Singh, Sumit K. Rastogi, Arun K. Sinha. State Key Laboratory of Silicate Materials for Architectures, and School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, 205 Luoshi Road, Wuhan 430070, P.R. SO ). firstname.lastname@example.org, b -Activated Efficient Beckmann Rearrangement of Ketoximes for Accessing Amides and Lactams.
Files available from the ACS website may be downloaded for personal use only. -mediated transformation of 2'-hydroxyacetophenones to benzo-oxetes. 2-Azidoethane-1-sulfonylfluoride (ASF): A Versatile
At its simplest, it is useful way of converting alkanes, which are relatively inert and thus low-valued, to olefins, which are reactive and thus more valuable. This article is cited by
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formally request permission using Copyright Clearance Center. Room temperature clickable coupling electron deficient amines with sterically hindered carboxylic acids for the construction of amides. One‐Pot Substitution of Aliphatic Alcohols Mediated by Sulfuryl Fluoride. Catalytic tests on methanol, ethanol, and 1- and 2-propanol at 400 °C supported the proposed relative selectivity; besides, the recorded alcohol total conversions and product yields agree well with what was proposed by the DFT reaction profiles, thus demonstrating the predictive capability of the chosen electronic structure approach. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Fundamental and Computational Sciences Directorate and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, PO Box 999, Richland, Washington 99352, USA, b This straightforward transformation of sp3–sp3 (C–C) bonds to sp–sp (C≡C) bonds requires only inexpensive and readily available reagents (no transition metals) under mild conditions. China, School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Hefei 230009, P.R.
to access the full features of the site or access our, Physical Sciences Directorate and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. The crude alkynes are sufficiently free of impurities to permit direct use in further transformations, as illustrated by regioselective Huisgen alkyne–azide cycloaddition reactions with PhN3 to give 1,4-substituted 1,2,3-traiazoles (16 examples, up to 92% yield) and Sonogashira couplings (10 examples, up to 77% yield). it in a third party non-RSC publication you must )–H of primary alcohols with the C(sp it in a third party non-RSC publication you must
"Reproduced from" can be substituted with "Adapted from". 2 mediated transformation of pyrazolones into pyrazolyl fluorosulfates. A cascade process for directly converting nitriles (RCN) to cyanamides (RNHCN) Dehydration dominates at lower ethylene glycol coverages (<0.2 ML) and plateaus as the coverage is increased to saturation. or in a thesis or dissertation provided that the correct acknowledgement is given Installation of -SO
OH) to Nitriles (RCN) Mediated by SO Making Carbonyls of Amides Nucleophilic and Hydroxyls of Alcohols Electrophilic Mediated by SO2F2 for Synthesis of Esters from Amides.
Dehydrogenation is observed primarily at higher ethylene glycol coverages (>0.2 ML). Bruce.Kay@pnnl.gov, Zdenek.Dohnalek@pnnl.gov. 2 Information about how to use the RightsLink permission system can be found at do not need to formally request permission to reproduce material contained in this Compared with the process of petroleum to ethylene, ethanol dehydration to ethylene is economically feasible. SO In all cases the Ref. Computing the relative reaction barriers with all electron DFT and split-valence basis sets for a panel of 11 alcohols suggested dehydrogenation to be the most active process catalysed by gallia for both primary and secondary alcohols despite its fundamentally acidic behaviour, which was previously suggested to foster dehydration. 2
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2 A SO2F2 mediated mild, practical, and gram-scale dehydroxylative transforming primary alcohols to quaternary ammonium salts. 2
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without permission from the American Chemical Society. 2 Box 999, Richland, WA, USA, Interfacial Phenomena in (De)hydrogenation Reactions, Instructions for using Copyright Clearance Center page. Revathi Lekkala, Ravindar Lekkala, Balakrishna Moku, Hua-Li Qin. 2 or in a thesis or dissertation provided that the correct acknowledgement is given Yongan Liu, Donghai Yu, Yong Guo, Ji-Chang Xiao, Qing-Yun Chen.
Dipartimento di Scienza ed Alta Tecnologia, Università degli Studi dell'Insubria, via Valleggio 11, 22100 Como (I), Italy The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting * Instructions for using Copyright Clearance Center page for details. article provided that the correct acknowledgement is given with the reproduced material. An in situ site titration experiment revealed that carboxyl groups were the active sites for the formation of dimethyl ether. It is the reverse of hydrogenation. Jing Liu, Shi-Meng Wang, Njud S Alharbi, Hua-Li Qin. P. Yan, X. Zhang, F. Herold, F. Li, X. Dai, T. Cao, B. J. M. Etzold and W. Qi, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, P. R. China, University of Chinese Academy of Sciences, Beijing, P. R. China, Ernst-Berl-Institut für Technische und Makromolekulare Chemie, Technische Universität Darmstadt, Darmstadt, Germany, Instructions for using Copyright Clearance Center page. A rapid access to aliphatic sulfonyl fluorides. Bis 2 2 is available on our Permission Requests page.
2 L. Izzo, T. Tabanelli, F. Cavani, P. Blair Vàsquez, C. Lucarelli and M. Mella, Dipartimento di Biotecnologia e Scienze della Vita, Università degli Studi dell'Insubria, via J. H. Dunant 3, 21100 Varese (I), Italy, Dipartimento di Chimica Industriale “Toso Montanari”, Università degli Studi di Bologna, Viale Risorgimento 4, 40136 Bologna (I), Italy, Consorzio INSTM, Research Unit of Bologna, Florence, Italy, Dipartimento di Scienza ed Alta Tecnologia, Università degli Studi dell'Insubria, via Valleggio 11, 22100 Como (I), Italy, Instructions for using Copyright Clearance Center page. One‐Pot Substitution of Aliphatic Alcohols Mediated by Sulfuryl Fluoride. This article is part of the themed collection: For reproduction of material from all other RSC journals and books: For reproduction of material from all other RSC journals. "Reproduced from" can be substituted with "Adapted from". Find more information about Crossref citation counts. Revathi Lekkala, Ravindar Lekkala, Balakrishna Moku, K P Rakesh, Hua-Li Qin. Transition-metal-free regioselective construction of 1,5-diaryl-1,2,3-triazoles through dehydrative cycloaddition of alcohols with aryl azides mediated by SO
http://pubs.acs.org/page/copyright/permissions.html. Dehydrogenation is observed primarily at higher ethylene glycol coverages (>0.2 ML). -amino-arylfluorosulfates. -activated Tiemann rearrangement.
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The catalytic activity for a range of interrogated (WO3)3 motifs (from unsupported clusters to nanoporous films) further sheds light onto the role structure and binding of (WO3)3 clusters with the support play in determining their catalytic activity. Chuang Zhao, Gao-Feng Zha, Wan-Yin Fang, Njud S. Alharbi, Hua-Li Qin. Fetching data from CrossRef.
Find more information on the Altmetric Attention Score and how the score is calculated. You’ve supercharged your research process with ACS and Mendeley! Get article recommendations from ACS based on references in your Mendeley library. Wan-Yin Fang, Gao-Feng Zha, Chuang Zhao, Hua-Li Qin. Dehydrogenation of cyclohexane was examined at 300 °C. To explore alternative applications of gallium(III) oxide and co-precipitated Ga(III)/M(II) oxides (MMg, Ca, and Sr), we investigate the relative dehydrogenation/dehydration activity of nanostructured gallia for alcohols via electronic structure calculations, reactivity tests and DRIFT-IR spectroscopy. SO Your Mendeley pairing has expired. a email@example.com, firstname.lastname@example.org.
This straightforward transformation of sp3–sp3 (C–C) bonds to sp–sp (C≡C) bonds requires only inexpensive and readily available reagents (no transition metals) under mild conditions.
-clickable Reagent for SuFEx and CuAAC Click Reactions. The coverage dependent yields of ethylene and acetaldehyde correlate well with those of water and hydrogen, respectively. Corresponding authors, a 2.
Direct synthesis of alkynes from inexpensive, abundant alcohols was achieved in high yields (greater than 40 examples, up to 95% yield) through a SO2F2-promoted dehydration and dehydrogenation process. What is the difference between dehydration and dehydrogenation? If you are the author of this article you do not need to formally request permission
E-mail: ) in chemical transformations. 2. Xu Zhang, Balakrishna Moku, Jing Leng, K. P. Rakesh, Hua-Li Qin. Guofu Zhang, Yiyong Zhao, Chengrong Ding. "Reproduced from" can be substituted with "Adapted from". mediated dehydrative cross-coupling of alcohols with electron-deficient olefins in DMSO using a Pd-catalyst: one-pot transformation of alcohols into 1,3-dienes. Find more information on the Altmetric Attention Score and how the score is calculated.
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