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Synthesis of α-Benzyloxyamino-γ-butyrolactones via a Polar Radical Crossover Cycloaddition Reaction.
Visible light-mediated dehydrogenative β-arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides. Stereoselective Synthesis of α-Linked 2-Deoxy Glycosides Enabled by Visible-Light-Mediated Reductive Deiodination. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. CHIMIA International Journal for Chemistry. Any queries (other than missing content) should be directed to the corresponding author for the article. Amide and Amine Nucleophiles in Polar Radical Crossover Cycloadditions: Synthesis of γ-Lactams and Pyrrolidines. Almudena Couce-Rios, Agustí Lledós, Gregori Ujaque. For instance, rare earth metal complexes catalyze the hydroamination of methylenecyclopropane to afford imines with ring opening (Eq.
PCET-Enabled Olefin Hydroamidation Reactions with N-Alkyl Amides.
Gold-Catalyzed Intermolecular anti-Markovnikov Hydroamination of Methylenecyclopropanes with 2-Pyridones. Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes. Hydroamination reactions of alkenes represent additions of N-H bonds across carbon-carbon double bonds. Wei Wei, Leilei Wang, Pengli Bao, Yun Shao, Huilan Yue, Daoshan Yang, Xiaobo Yang, Xiaohui Zhao. N′ Photocatalysis with Quantum Dots and Visible Light: Selective and Efficient Oxidation of Alcohols to Carbonyl Compounds through a Radical Relay Process in Water. Jacky C.-H. Yim, Jason A. Bexrud, Rashidat O. Ayinla, David C. Leitch, and Laurel L. Schafer . system.
Visible-Light-Mediated Annulation of Electron-Rich Alkenes and Nitrogen-Centered Radicals from N-Sulfonylallylamines: Construction of Chloromethylated Pyrrolidine Derivatives. Photophysics and Photochemistry of Conformationally Restricted Triarylmethanes: Application as Photoredox Catalysts. Various difunctionalizations of acrylamide: an efficient approach to synthesize oxindoles. Nathaniel Corrigan, Sivaprakash Shanmugam, Jiangtao Xu, Cyrille Boyer.
Visible-Light-Mediated Dehydrogenative Cross-Coupling: Synthesis of Nonsymmetrical Atropisomeric Biaryls. Liangbin Huang, Matthias Arndt, Käthe Gooßen, Heinrich Heydt, and Lukas J. Gooßen . -Donor. Mechanistic Insights into First-row Late Transition Metal-catalysed (formal) Hydroamination of Unact... Co(thd)2: A Superior Catalyst for Aerobic Epoxidation and Hydroperoxysilylation of Unactivated Alken... ChemInform Abstract: Environmentally Friendly Catalysis Using Supported Reagents: Catalytic Epoxidat... Isomerization of Terminal Alkenes to (Z)-2-Alkenes via Cobalt Catalysis. Jingnan Zhao, Fan Yang, Zongyi Yu, Xiaofei Tang, Yufeng Wu, Cunfei Ma, Qingwei Meng. To illustrate this progress, the review will mostly focus on recent develop-ments in the field of intermolecular hydroamination of alkynes. Rory C. McAtee, Edward J. McClain, Corey R.J. Stephenson. C–N bonds are ubiquitous in organic molecules and their formation is crucial in organic synthesis. The addition of an amine NH‐functionality to alkenes (including vinyl arenes, conjugated dienes, allenes or ring‐strained alkenes), the so‐called hydroamination, represents a simple and highly atom‐economical approach for the synthesis of nitrogen‐containing products. H Facile and Green Synthesis of Saturated Cyclic Amines. Lena Pitzer, Frederik Sandfort, Felix Strieth‐Kalthoff, Frank Glorius.
Pushing the boundaries of C–H bond functionalization chemistry using flow technology. Alberto Vega‐Peñaloza, Javier Mateos, Xavier Companyó, Margarita Escudero‐Casao, Luca Dell'Amico. Hao Wang, Jinyi Tao, Xinpei Cai, Wei Chen, Yueqi Zhao, Yang Xu, Wang Yao, Jing Zeng, Qian Wan. The catalytically active complexes are soluble in perfluoroheptane and form in situ from ligand 1 and the Mn²⁺ complex 2 with polyfluorinated carboxylate ligands (fluoroponytails). Der Thieme.de Webshop: Bücher, E-Books, Fachzeitschriften, elektronische Lösungen und mehr finden Sie unter, Bücher versandkostenfrei innerhalb Deutschlands, Selenium Tetrachloride Catalyzed Iodination of (Hetero)Arenes, Pd-Catalyzed Synthesis of N-Allyloxypyrrolidinediones, A Novel Approach to Diarylated Esters and Phosphonates, One-Pot Access to 2-Aryl-3-(arylmethyl)chromones, Benzoazepinoindoles – A New Class of Heterocycles, Professor M Kevin Brown Appointed as Volume Editor for Science of Synthesis Volume 23, 1,2,4,5-Tetrazine Derivatives from Arylsulfonylhydrazones, Mono- and Dihalogenation of 2-Aminopyrazine, Novel Approach to Antihistamine-type Scaffolds, Prof. Xuefeng Jiang and Dr. Ming Wang New Science of Synthesis Volume Editors, Professor Christoph Marschner New Science of Synthesis Volume Editor, Ten aspiring young chemists win poster prizes at OMCOS 20, An Improved Synthesis of 2,5-Disubstituted Tetrazoles, Cu(II)-Catalyzed Beckmann Rearrangement of Ketones, Allylic C–H Alkynylation via Copper Photocatalysis, Synthesis of Dumbbell-like Amine-Functionalized Bis-C60 Fullerene, Total Syntheses of (+)-Alexine and Related Alkaloids, Poster Prize awarded at Bioheterocycles 2019, Science of Synthesis Editorial Board Meeting 2019, Poster Prize awarded at Twente / Mainz Symposium, First Total Synthesis of Artekeiskeanol A, C and Altissimacoumarin D, Iodoglycosylation and Iodocarboxylation of Glycals, Gold(III)-Catalyzed Synthesis of N,N-Aryl,Benzyl-amines in Water, Synthesis of Fatty Acid Intermediates via Hudrlik–Peterson Reaction, Recyclable Graphene Oxide Nanosheet Supported Catalyst, A Stereoselective Synthesis of the ACE Inhibitor Trandolapril, New Entry to 3-Arylglutaconic Acid Derivatives, Asymmetric Synthesis of α-Hydrazino Ketones, Synthesis of (–)-Boschnialactone and γ-Lycorane, Synthesis of the ABC-Ring System of Various Alkaloids, Synthesis of 4-(Arylmethyl)proline Derivatives, Efficient Synthesis of a 5α-Reductase Inhibitor, Epoxidation of a Cyclic Allyl-Amine by a Bifunctional Peracid, Radiochemical Synthesis of 2-[18F]Fluorophenylalanine, Asymmetric Mannich-Type Reaction of an α-Trifluoromethyl Amide, Chemoselective Aerobic Oxidation of Benzylic Alcohols, One-Pot Reductive Conversion of Aldehydes into Acetic Esters, Visible-Light-Induced Adamantylation of Azoles, Thieme Chemistry provides 700,000 structures to PubChem, Psychiatrie, Psychotherapie und Psychosomatik, Fachcommunity für Geburtshilfe und Frauenheilkunde.
The scope of the nitrogen-containing reactant includes amines, azoles, and N-protected substrates. You can request the full-text of this article directly from the authors on ResearchGate. The Hofmann reaction involving annulation of Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing.
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